(8) Iveta Benesova/ Barbora Zahlavova Strycova v Vania King/ Yasmin Schnack
Janette Husarova/ Ksenia Pervak v Olga Govortsova/ Mandy Minella
Andreja Klepac/ Anastasia Rodionova v Jill Craybas/ Julia Goerges
Hao-Ching Chan/ Yung-Jan Chan v (9) Nuria Llagostera Vives/ Maria Jose Martinez Sanchez
(15) Irina-Camelia Begu/ Monica Niculescu ROU v Elena Baltacha/ Anne Keothavong Su-Wei Hsieh/ Sabine Lisicki v Laura Robson/ Heather Watson
Anastasia Pavlyuchenkova/ Lucie Safarova v Flavia Pennetta/ Francesca Schiavone
Naomi Broady/ Johanna Konta v (3) Kveta Peschke/ Katarina Srebotnik
I don't believe she will play doubles at the Olympics if Andrea is able to compete with Julia.
Her match isn't listed on any of the streaming sites, not looking good
It is on LSH, even with actual streaming links already. The match will only be broadcast on the BBC Red Button channels, so the stream won't start very long before play begins.
You also might want to take a look at (and bookmark) filmon.com, to have a reliable source for the main BBC(2) programming. It's a streaming service similar to Zattoo, where all the British FTA channels are always available.