Pat Rafter Arena (Not Before 7:00 P.M Brisbane Time)
 Maria Sharapova (RUS) VS Caroline Garcia (FRA)
Check the times according to where you live so you'll get to see Masha's debut in 2014.
Oh, and Dimitrov plays Robin Hasse immediately after the conclusion of this match.
EDIT: ^ Beat me to it.
oh well. Two is better than one.